Madder & Chalk

Most sources agree that you need chalk to unlock the true reds of madder. I’ve always had a difficult time reconciling that with my own results, so experiments were called for.

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I spent the past summer with a lot of experimental dyeing, and one of my themes was how chalk affects madder red.

Earlier in the year, I had experimented to see if I could remove the yellow tones from madder by soaking the madder in hot or cold water and discarding that water before dyeing (extraction) but according to my experiments, that’s not possible.

So the problem remained: sometimes I get a nice saturated red, other times a less saturated, more orange tone, although I use the same dyeing method.

My earlier experiments didn’t show a large difference between reds from rain water and tap water. The red with rain water is only slightly better than the one with tap water, but that is because the tap water is soft here.

But I have heard from several other Danish dyers that they have hard tap water, and that destroys the madder reds for them. I’ve also seen that myself where I used to live before, in a place with hard water.

This observation is quite consistent – but – is directly contradicted by a large body of work by many different authors, of mostly English-language dyeing books. Here’s a small selection from different authors:

“Chalk or slaked lime is added, particularly in areas with soft water.” John & Margaret Cannon: Dye Plants and Dyeing, p. 76.

“Add a tablespoon of ground limestone or chalk dust.” Rita Buchanan: A Dyer’ Garden, p. 52.

“If the water is deficient in lime, brighter shades are got by adding a little ground chalk to the dye bath.” Ethel Mairet: Vegetable Dyes, p. 42.

“Powdered chalk or limewater should be added to the dye-bath if the madder is ‘acid’.” Quote from Hellot’s “Art de la teinture des laines et étoffes de laine” in Dominique Cardon: Natural Dyes, p. 113.

I could go on like this. Source after source points out that chalk should be added. Some say if there is not “enough” or ir if the madder is “acid”, others just always add it.

It’s not clear where the idea comes from, but it seems to have been in circulation for a very long time. Hellot, quoted by Cardon, published his “Art de la tenture” in 1750, and it has been a very influential book.

The plant it’s all about – madder, Rubia tinctorium. Here a second-year plant growing in my dye garden in the middle of the summer.

In order to understand the effect of madder and chalk, I carried out a series of dyeing experiments on wool.

In all experiments, the proportion of madder to wool was 1:1, and I dyed at approx. 55 degrees C. I let the madder soak in water overnight, then dyed in that dye bath. During dyeing, I held the temperature for an hour, then let the yarn cool off in the bath until the next day.

First, I wanted to find out if it is chalk in tap water that affects the madder color, or something else. And by “something else”, I mostly mean iron, which may be present in tap water, and can affect colors a lot, when present even in small amounts.

For comparison, I began by dyeing a skein in tap water.

Then, I added chalk (from a garden center) in the amount of 4 g/L. That corresponds to about 2 Tsp in 10 L of water, giving a very slightly elevated pH of 7-8 instead of plain 7. The amount was just a guess, at that point in my experiments, I didn’t have a good idea of how much to use. I tried adding that amount both to tap and rain water.

Finally, I tried quicklime, which is a very strong base. So I neutralized it with a strong acid, since base destroys wool.

The results from that first round are below. On the left, yarn dyed in tap water, a paler red, the usual shade with tap water. When I add chalk to tap water, the color darkens slightly, just slightly. With rain water and chalk, the color is a bit lighter that with tap water alone, but very similar. So the conclusion so far is that chalk is the component in tap water that affects the color, not something else like iron.

But to be more sure, and having read that chalk for the garden can contain iron, I also tested quicklime. Calcium in tap water and in chalk for the garden is CaCO3 (calcium carbonate). Quicklime, on the other hand, is Ca(OH)2 (calcium hydroxide), a strong base. It was impossible to measure accurately, so I just took some of the chalky water in my bucket of quicklime and added it to demineralized water. This way, no other metals or minerals are present. I then neutralized the quicklime with a strong acid (I don’t remember which one).

The result of the quicklime experiment is seen at right. A very dusty pale red. So my conclusion so far is that yes, chalk has an effect, which is to make madder red paler and dustier, not more intense red. And yes, the component of tap water to affect the color is chalk. And the more of it (the harder the water), the larger the effect.

Madder dyeing in tap water, tap water with added chalk, rain water with added chalk, and demineralized water with neutralized quicklime.

After this first round of experiments, I started thinking that I had added too much chalk. It might just be that there was a good effect at a certain low amount, but that too much chalk added could ruin the color. Having searched through my entire dye library, I finally found the figure 1-2% mentioned by Mairet. Most books just give nonsensical directions such as “a spoonful per dye pot”.

In order not to miss the sweet spot, I tested addition of 0.2, 1, 5, and 10% chalk. The result below was not entirely what I had expected. There really is no difference between dyeing in pure rain water and adding up to 5% chalk. The color began changing very slightly at 10% added (becoming paler) but the difference is so small that the photo does not capture it.

Wool dyed with madder in rain water with no chalk added, and with 0.2, 1, 5, and 10% chalk added.

I couldn’t really decide if this was a good or bad result. Chalk in relevant amounts does not have an effect. It does not help unlock the good reds, but it also doesn’t do any harm.

But if all the English-language dyeing books are wrong, are the Danish dyers then right? Does the red color improve with less chalk? Below, a comparison of madder dyeing in rain water, tap water, and demineralized water. There is the usual difference between rain and tap water, the former giving the better red.

I took extra care with the yarn dyed in demineralized water. After mordanting, done in tap water as usual, I washed the yarn in rain water several times, and also cleaned the glassware for dyeing in rain water. That treatment gave the best red in the entire experiment, so I have to conclude that less chalk gives better red.

Dyeing with madder in rain water, tap water, and demineralized water. Tap water gives the least good red, demineralized water the best.

Below, I’ve shown all the colors in one picture so it’s easy to compare them.

All colors from the test together. All are 1:1 madder on wool, and cards grouped together were dyed simultaneously in glass jars over a water bath.

So my result is very clear – less chalk gives better reds. But one mystery does remain. Why do all dyeing books from the last 3 centuries state that madder gives better reds when chalk is added?

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Madder’s Family

Madder has several relatives that are also rich in useful reds. These plants are native here in Denmark, and have been used as red dyes a very long time back.

Believe it or not, the year is drawing to a close. So, I want to try to summarize all the many dyeing experiments I did over the year.

This summer, I searched for madder’s relatives, to find as many as possible. Madder, Rubia tinctoria, belongs to the madder family (Rubiaceae) in which you also find the bedstraws (the genus Galium).

Galium species do not contain as large amounts of red dye as cultivated madder does, but several of the species grow wild here in Denmark, and their historical use is well known.

Madder plant growing in my dye garden.

The first Galium species to present itself was cleavers (Galium aparine). It’s everywhere! Anybody who has ever walked outside surely know this plant. Or at least its seeds. They are extremely good at clinging to clothing and dog fur. The whole plant is covered with clingy hooks – the very same that cultivated madder has.

My attempt to dig up cleaver roots quickly came to an end. The roots have the thickness of sewing thread, so a lot of digging is required. But the roots are said to contain dye, so I’m keeping them on my list of maybes.

Cleavers up close. You can see the characteristic clingy hooks on the seeds. The very same that madder is covered with.

Lady’s bedstraw (Galium verum) is the plant mentioned by most natural dyeing books. I tried growing it in the garden this year, seeding it outside in the spring, but nothing grew.

Whenever you’re looking for a specific plant or mushroom, but haven’t found it yet, it’s simply invisible. But, once you find it, you start seeing it everywhere. The relationship between Lady’s bedstraw and myself developed exactly like that over the summer. Once I found it, it was everywhere! For example this coastal grassland:

Coastal grasslands with very sandy and infertile soil, perfect for Lady’s bedstraw. I took this picture in a region of Denmark called Mols.

 

Lady’s bedstraw truly thrives in the nutrient-poor, sandy soil, along with yarrow and St. John’s wort.

Lady’s bedstraw growing in a big cluster.

Unfortunately, several walks with a shovel only yielded a very small handful of Lady’s bedstraw roots – so little that my scale didn’t register. Like with cleavers, the roots are extremely fine, and they tangle up with roots of grass etc. In combination with stony, sandy soil, the digging job gets hard. To get your hands on a larger pile of these roots, I suspect you have to grow them in a well-prepared sandy soil without obstacles. Anyway, I tried dyeing with my small handful of roots, but it gave almost no color.

But then, on a forest walk, this plant turned up – hedge bedstraw (Galium mollugo):

Flowering hedge bedstraw photographed in July.

Hedge bedstraw is also mentioned by different books as a dye plant, so I brought out the shovel once more. Again, it was difficult. The forest soil is obviously full of tree roots that make digging quite impossible. But I managed to get a couple of handfuls of roots, mainly because hedge bedstraw roots are not that thin. I dug up the roots on July 9th. The next day, after cleaning, the slightly dried roots weighed 30 g.

My pile of hedge bedstraw roots, with reds clearly showing under the out bark.

I soaked the roots in cold water overnight, then dyed my usual alum mordanted 12-gram skeins of Fernris to test the dye. I removed the overnight water because Jenny Dean does, but I should have concluded from my madder experiments that it is not necessary to do so. The water used to soak the roots overnight simply contains a small amount of dye, with the same properties as the dye you extract when you heat the roots in water (the small 6-gram skein laying across the others in the picture below was dyed with the discarded water).

Then, I dyed alum mordanted 12-gram skeins in a 1st and 2nd dyebath, in exactly the same way as if it had been madder: heating up to 60 degrees C, then leaving the yarn in the dyebath until the next day. The first bath gave a convincing red-orange, which would not have been a surprise had it been madder I was dyeing with. The dye is less abundant in hedge bedstraw than in madder, but the difference is actually smaller than anticipated. Here, I used 30 g of roots on 12 g of yarn, with madder, you would get this shade with less than 100% weight of fiber.

After the second bath, which also worked well, I was evidently feeling on top of things, and threw in a 50 g skein. There was not much dye left, but to extract everything that was there, I left the bath with yarn in a jar outside. That was in mid-July.

A couple of times, I heated the entire jar over a water bath to give the process a helping hand, but the rest of the time, it was just standing there. I turned over the yarn to get an even dye, and for a while, it also fermented. Both time and fermentation should help release the dye. Also, I imagine that a skein of yarn in the bath will soak up the dye as it is released, permitting more to come out (alizarin has a rather low solubility in water). In any case, my large skein stayed in the jar for 6 weeks, and turned out a pleasing coral color. And, the dye bath ran clear, so there was probably nothing left in the roots.

Dyeing with roots of hedge bedstraw (Galium mollugo). 1st bath (left), 2nd bath (middle), and the large skein on the right is fermentation of the 3rd bath. The small skein across was dyed in the water used to soak the roots overnight.

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Knitting Better Stripes

Knitting stripes is so addictive. Here’s a simple technique to make the color change from one stripe to the next smoother when knitting in the round

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I’m working on the design for a girl’s dress in multicolor stripes. It has a turned picot edge and it’s knit top-down. The first prototype is knit in Fenris (100% wool, 450 m / 100 g or 492 yd / 3.53 oz) dyed with madder, indigo, woad, Japanese indigo, and a series of purples from cochineal overdyed with indigo.

Dagmar running over a harvested field on one of the last days of summer.
The dress has a round yoke and turned picot edges along neck, arm, and lower hem. Notice the cluster of trees in the left side of the photo – a burial mount from antiquity.

In order to make the color change from one stripe to the next as nice as possible (even though it’s on the back), I used this technique:

After changing to a new color, first knit an entire round, then remove the end-of-round marker.

The first stitch that was knit with the new color is now the right-most stitch on the left needle – the stitch you were just about to knit. Insert the left needle through the stitch right under it from the right side. Don’t let go of the stitch that was already on the needle. You now have two stitches instead of one, and they are not the same color:

Two stitches together, different colors because they come from two different stripes.

Now, knit the two stitches together (with a k2tog) and replace the end-of-round marker. The change of round has now moved one stitch to the left, but that is OK.

The two stitches knit together, and the marker replaced.

The result is this:

The yoke of the dress with jogless stripes.

Not perfect, but a huge improvement over just cutting the old yarn and adding the new.

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Red Madder

Madder is one of the most ancient dyes, and one that is described in pretty much any book on natural dyeing. But every book seems to give a slightly different method for obtaining the sought-after madder red. There’s only one thing to do – experiment!

A bunch of madder dyed skeins. They’re all dyed in slightly different ways, so the colors have turned out differently.

Madder was one of the first natural dyestuffs I tried just when I began learning about natural dyeing, many years ago. I followed Jenny Dean’s “Colours from Nature”, the first book I bought back then (now, of course, I have a largish library on natural dyeing).

Dean gives a dyeing method for larger pieces of madder root, not powdered root. She rinses the root in cold water, then boiling water, and then adds the water for the actual dye bath. I tried her method for my first attempts with madder, but only got a series of tan/coral shades. Sometimes slightly more pink, sometimes more towards orange.

After my first attempts, I was ready to just give up. Coral was not exactly my favorite color, and I didn’t make any further attempts with natural dyes. That was until I happened to talk to some dyers at iron age and viking markets. One of them told me, that she always got good reds with madder by using destilled water.

After that, I happened to find a copy of a classic Danish dye book from 1972, “Dyeing with Plants” by Ester Nielsen. Nielsen steeps madder for 24 hours, and mentions nothing about changing the water at any point. Also, she mentions nothing about the type of water. Over time, I arrived at a variant of Nielsen’s method, using rainwater instead of distilled water because rainwater is free. I leave the madder to steep overnight in my dyepot, add alum mordanted wool, heat slowly to 55 C, and then wrap the pot in a blanket and leave it until the next day. So, yarn and madder in the pot together, and no changing the water.

I’ve achieved many clear reds with that method, but sometimes, the color has turned out more orange than red. That’s the case with the yarn for this hat:

Brisingamen hat in madder dyed yarn.

I do like orange, but it’s red you’re after with madder. Also, I’ve become increasingly confused the more I’ve read about madder dyeing, and I am not the only one. As mentioned, Dean uses a hot extraction (a soak in water that is discarded) whereas others, for example Ecotone Threads use a cold extraction.

Madder contains many different dye compounds. According to “Handbook of Natural Colorants” by Berchtold & Mussak, more than 35 different anthraquinones have been detected in madder (anthraquinones are the type of molecules that alizarin, the important red in madder, also belongs to). The different dye compounds have slightly different colors, so the the point of (cold or hot) extraction would be to remove some of the yellow or brownish ones.

I decided to test, whether I could get rid of my orange reds by using an extraction method. For this test, I’ve used my usual 12-gram skeins of Fenris (100% wool) mordanted with 10% alum. In all the experiments, I used 12 grams of madder powder per skein, leaving the madder in the dyepot the entire time. A few writers say that the madder should be removed from the dyepot before fiber is added, but most agree to leave it in.

According to Liles’ “The Art and Craft of Natural Dyeing”, alizarin has a very low solubility in water, and that’s why the madder should stay in the pot. As alizarin in solution is taken up by the yarn, more will be released from the madder. In all cases, I dyed the yarn by heating yarn and madder to 55 degrees C keep it there for 1 hour, and then leave the yarn in the dyebath overnight.

In my little experiment, I tested the following, both with rainwater and tap water: steeping the madder overnight and dyeing in the same water, filtering out the madder and dyeing with it in new water, and finally pouring boiling water over the madder and then dyeing with it in new water.

Filtering a small amount of madder in an old fashioned coffee filter.

Results below:

1: Madder steeped overnight in rainwater, yarn dyed in the same water.

2: Madder steeped overnight in tap water, yarn dyed in the same water.

3: Madder steeped overnight in rainwater, filtered, run-off removed and yarn dyed in new rainwater.

4: Run-off from 3 (the liquid that ran through the filter).

5: Madder steeped overnight in tap water, filtered, run-off removed and yarn dyed in new tap water.

6: Run-off from 5 (the liquid that ran through the filter).

7: Poured boiling water over the madder, filtered immediately, yarn dyed in new rainwater.

8: Poured boiling water over the madder, filtered immediately, yarn dyed in new tap water.

9: Run-off from 7 (not repeated for 8, as it would be identical.

The madder dyed skeins – theme and variations.

Skein 1 is dyed with just one volume of rainwater, which is my usual method. Luckily, skein 1 is one of the good reds in my test. Skein 2 is the same method, but using tap water. Skein 1 is only a slightly bit redder than skein 2, so using rainwater instead of tap doesn’t seem to have the importance that I thought. I measure pH of both baths, and they were both neutral after steeping overnight.

Skein 3 and 5 are dyed with madder that was steeped overnight, and then filtered to remove the first volume of water. If it was true that steeping and removing the water would remove yellow and brown tones, then skein 1 and 3 (both dyed in rainwater) and skein 2 and 5 (both dyed in tap water) should be different, but they are not. My conclusion is, that cold extraction does not remove yellows and browns.

That conclusion also seems to be correct when you look at skein 4 (rainwater) and 6 (tap water), which are dyed with the run-off from 3 and 5. If the extraction removed yellows and browns, then skein 4 and 6 should have those colors, but they don’t. They are tan/coral, exactly the kinds of colors I normally get from second, third and later afterbaths. So this could mean that cold extraction just removes a small fraction of the overall color present in madder.

Finally, the hot extraction. Skein 7 (rain) and 8 (tap) are dyed in new volumes of water added to the madder after the hot extraction. They are weakly colored, and the shades are very similar to those of skein 4 and 6. So most of the color is just gone after the hot extraction, and has ended up in the run-off that was used to dye skein 9.

Skein 9 has a good, saturated red-orange color, which is not that surprising. Temperature is the only factor that more or less all authors agree on. The temperature mustn’t get too high, as that brings out orange or terracotta tones, exactly what I’m seeing here. If  the light fastness turns out to be good, then this is actually a very good method for dyeing orange.

It’s nice to observe that this little experiment fits with my very earliest observations with madder. Deans method gives skein 8, a pale tone that would definitely be disappointing if you are trying to dye red.

So, in summary, the conlusions of my little experiment are:

Reds obtained with rainwater and tap water are not very different, and rainwater gives a red that is only very slightly better than the red with tap water. This conclusion is for my tap water, and may be entirely different elsewhere.

Cold extraction is not efficient for removing yellows, and hot extraction removes almost all the color.

I usually keep the temperature around 55 degrees C, but I have never checked myself to see how sensitive the color is to temperature. And I haven’t even begun to look at pH and calcium. My next experiments will be on those factors.

A Herd of Hats

What’s the collective noun for hats? “Herd”? “Flock”? “Mob”? “Head”? Or, in my case, “parliament”, or even “pandemonium” may even soon be appropriate. I can’t seem to stop knitting them.

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I’ve been working on two new designs for hats, a lacy one that leapt out at me from a Japanese pattern dictionary, and one in stranded knitting that came about by swatching. Yes, swatching.

Brisingamen is inspired by a Japanese pattern, and knit in two layers all over. The entire inside is knit in Bestla, a 35/65 mix of silk and merino, the entire outside is Norne, my 1-ply pure wool lace yarn. It took a bit of hard thinking to come up with a way to line both the hem and the rest of the hat – in the end, I went with two provisional cast ons. That may sound incredibly complicated, but it’s really not. And the result really is excellent. Since the gauge is small, the double fabric is thin, but very warm, even when it’s windy.

Here’s Dagmar on a snowy day a while ago, wearing the first prototype, knit in undyed yarn. It turned out too small for me, but fits her just perfectly.

Dagmar happily wearing the Brisingamen prototype.

For the final version, I only had to do small recalculations. A triple cable replaces the single line of twisted stitches between motifs, and the rib is longer. Here it is, almost done, in yarn dyed with 1:1 madder. I’ve dyed with madder on pure wool so many times, and still love how it takes the color. Silk merino takes the same dye in a slightly different, no less delicious, way. Perhaps it is the silk sheen that alters the look just slightly.

Brisingamen hat, the outer layer is pure wool, the inner silk-merino. Both dyed with madder root.

Folkvang is a tam that was inspired by Bohus patterns. Since I first read about Bohus patterns, I’ve wanted to make something using them as a starting point.

I started swatching to try patterns out. In the beginning, I wanted an arched pattern, so that’s how the swatch starts out (right side). But the arch didn’t behave, and I realized that you would have to work 3 colors in one row to make an arch that separates areas with two different background colors. I hate knitting 3 colors at a time, so I continued the swatch with rectangular shapes.

First, a white rectangle on a blue and green background. It’s OK, but the purl stitches on the long edges don’t add anything. Next, a blue rectangle on beige background. Purl stitches inside the rectangle add texture that makes the pattern more interesting. Now, I was on to something. I changed to white background, kept the dark indigo blue as the contrast color, and added in a bright green band of background color. I was getting close, and was finally happy with the pattern when I let the white background peek into the purled inside of the rectangle, and softened the bright green with a bit of beige.

The Folkvang swatch. White background with contrast colors blue (indigo), dark green (tansy and indigo), beige (velvet pax 2. bath), and bright green (reed flowers).

The vertical lines of blue purl stitches just beg to be lined up with purl stitches of a corrugated ribbing, so that’s what I did:

The Folkvang tam, flying off the needles.

The hem is lined with silk-merino. The outer part is knit in Fenris, which is excellent for color knitting, but really not that soft.

In order not to break up the corrugated ribbing when progressing from the hem to the main body of the hat, I used a new (I think?) way of closing the hem in color knitting.

In the photo below, you see the corrugated ribbing in front. The provisional cast on is undone, and the live stitches put on a needle, sitting behind the work. Now, holding the yarns appropriately for color knitting (blue is my dominant color, so it’s towards the left because I knit continental), I purl the purl stitch with blue, then knit together 3 white stitches with white, one from the front needle and two from the back. This leaves the purl columns unbroken, very satisfying to the obsessive knitter.

Closing the hem in color knitting.

Vindauga Baby

The design theme from my Vindauga Blanket just stayed in my brain after I knit the first one, demanding to be knit in more variations! And when that design theme met with my experiments in 2-dimensional gradients (or matrices), the result was the Vindauga Baby Blanket, which I’ve finally managed to publish the pattern for.

You can buy the Vindauga Baby Blanket pattern on Ravelry. I’ve also dyed a small number of kits, you can find them at my Etsy shop. The colorways are purple-blue (dyed with cochineal and indigo – sold out), red-blue (dyed with madder and indigo) and green-blue (dyed with weld, mugwort, and indigo).

From a set of 9 skeins of matrix-dyed yarn (on the left) to the Vindauga baby blanket.

I’ve now written the pattern, had it test knit, and corrected over and over again. It’s finished, and now published in Danish and English. I’ll be the first to admit that actually finishing a pattern is not my favorite part of the process from idea to pattern. But if I don’t pull myself together at some point, then my ideas end up as just that – ideas in my head.

But dyeing the matrix mini skeins is a lot of fun. I’ve worked with these 2-dimensional gradients for some time now, but it’s still difficult to get them just exactly right!

First, I dye gradients of red, pink, or red with madder, cochineal, weld, tansy, or mugwort. I make 3 skeins of each. Then, I overdye with an indigo gradient, giving each of the 3 identical skeins a different indigo overdye. This may not sound difficult, but both steps are hard to control.

When dyeing with cochineal and madder, I find that the first bath always gives a more intense color than the second one. But sometimes, the second and third give about the same. It’s also difficult to control the exact shade of blue with indigo dyeing. One factor is how long you dip skeins in indigo, another factor is the number of dips. But the amount of available indigo in the vat also changes over time. Even after making many sets of matrix dyed skeins, it’s still a challenge!

indigo overdye
Yellow, red, and white skeins soaking on the left. On the right, similar skeins in an indigo bath. The temperature is 52 degrees, pH is 9-10. Everything is under control!

See projects on Ravelry:

Curly Dock Mordant

Dock or sorrel are useful plants for mordanting – this was a fact that I’d gotten from reading and made a mental note of. I couldn’t remember where I read it, so I decided to just go ahead and try it. I picked curly (or curled) dock (Rumex crispus) in the roadside around July-August. Curly dock is a tall plant with a reddish seedhead.

rumexcrispus
The seeds of curly dock.

Curly dock can be distinguished from other related species from the fact that its seeds are enclosed by three petals that have a growth on the outside that looks like a seed but is not.

rumexcrispus_zoom
Enclosed seeds of curly dock.

I used about 100 g of stalks with flowers for a test skein of about 12 g of wool. I boiled the curled dock the first day and let it cool off. The next day, I heated the yarn in the sorrel bath to just under boiling, then let the yarn cool off in the sorrel bath (for a couple of days in the end, because I had other fish to fry). After the sorrel mordanting in the dark red sorrel soup, the yarn was coral red.

skraeppebejds
The concoction of curly dock, and yarn treated with it.

Finally to the dyeing part of the experiment. I dyed my sorrel mordanted yarn plus two other 12-g test skeins (one unmordanted and one mordanted with 10% alum, my standard mordant) with madder. The dye bath was 40 g of madder root in rainwater, and you can see the result below. As expected, the alum mordanted wool is an intense madder red, but the unmordanted and sorrel mordanted wools are the exact same shade of orange (and a nice orange I think). But I’m going to call this a failure, since the sorrel mordant didn’t make a difference from no mordant.

Alum treatment gives the usual madder red – no mordant or treatment with curly dock both give orange.

So what went wrong? In the end, I realized that I read about sorrel mordant in India Flint’s “Eco Colour”, the exact information she gives is:

“Dry and grind the roots and mix with water to make a tannin-rich soaking solution. The leaves of this genus are also rich in oxalic acid. Even the dried seeds have mordant qualities.”

This doesn’t completely solve my mystery, though. The roots contain tannin, which only works as a mordant on plant fibers, not wool. But I used the flower stands with leaves, which (like rhubarb leaves) contain oxalic acid, which should work as a mordant on wool. Maybe the amount was just too low? I have to try tris again next year.

Madder Love & a FO

Madder red has been used by humans for millennia. Or, as someone much more eloquent that me put it: “Madder’s diary goes back as far as history’s earliest written pages” (Brian Murphy in “The Root of Wild Madder”).

Whenever I dye with madder, and stop to really think about its history, I’m quite fascinated. Yes, the colors from madder are varied and wonderful, but when you know more about its history and chemistry, then you see more than just color!

At the time of the ancient civilizations around the Mediterranean (Romans, Greeks, Phoenicians), there was an extensive trade in dyestuffs: madder, indigo, and Tyrian purple. This was taking place as early as the 12th century BC (for more details about this, see chapter 1 of “Handbook of Natural Colorants” a quite expensive book, but you can see an excerpt here which includes chapter 1).

In the context of oriental carpets, the history of madder is just as long. Classical Persian and Afghan carpets are dyed with madder (and its old friend indigo), and natural dyeing is the very reason that good carpets age gracefully, and even become more beautiful with age. In a naturally dyed carpet, the colors of wool change a bit differently with time, which adds a dimension to the pattern, called abrash. Notice the bands of lighter and darker background red in this carpet:

abrash

The main dye molecule (one out of maybe 20) in madder root, alizarin (AKA 1,2-dihydroxy anthraquinone), is a very good dye. It is one of the most light-fast natural dyes in existence, and its wash-fastness in complex with a metal ion is also very good (this is one of the reasons we use alum, which provides an aluminum ion).

The first few times I attempted dyeing with madder, I was quite disappointed because I couldn’t get the deep red. It turned out that my tap water was at fault. We Danes (at least here in the mainland) get our tap water from the underground where it rests on chalk deposits, so it is full of carbonates that interfere with the dyeing process. After switching to rainwater, I always get good results.

The first madder bath yields a deep red, and the next baths a series of progressively lighter coral shades. I’ve always loved the deep red, but the corals from the later baths have really grown on me.

And now I’ve finished a sweater for myself in such a coral shade of madder. The pattern is Folded by Veera Välimäki, and the yarn is Supersoft (575m/100g). I absolutely love the color, it really brightens the day when you are surrounded by people who mostly wear black and grey. The dye job is not very even, and that is actually what gives a nice fake abrash to my sweater. And I love how lightweight and comfy my it is, just 153 g. That’s because I knit the Supersoft quite loosely on a 3.5 mm needle

folded

The part that I’m less thrilled about is the fit of the sweater in the area around the shoulders. I followed the upper part of the pattern without modification, and the shoulders just don’t have enough fabric in them because the raglan seam is not long enough. I put the folds on the back of the sweater instead of the front, and I think that makes it much more flattering than the original.

Dyeing with Sorrel Root

Sometimes when I read something and there is one key word that doesn’t compute, it’s like my brain just jumps over the entire topic. Some time ago, searching for information on Xanthoria parietina and its pigment parietin, I came across information on the Rumex family. This is what I wrote back then

Parietin, Wikipedia informs us, is also found in the roots of curled dock (Rumex crispus). Jenny Dean lists the roots of curled dock, dock, and sorrel as sources of reddish browns, but I’m not sure if that has anything to do with its parietin content

but I didn’t connect it to anything, because I didn’t immediately see a plant in my mind’s eye. This summer, I actually went through the trouble of looking it up (sic), and found that it is a very common plant around here.

I gathered these plants in late June:

rumexplant

and I’m quite sure it’s Rumex acetosa (common or garden sorrel) which, according to this, you can also eat the young leaves from. It often grows in damp or even wet places. It is actually a bit hard to pull the root up, it’s easier the wetter the soil.

I tried dyeing with the roots according to the method in Jenny Dean’s “Wild Color”: I took 150 g of fresh roots, washed and chopped them, and at that point you can tell that they have some color in them:

rumexroot

I then soaked them overnight, although I’m not sure that step is necessary when using fresh roots. No color worth mentioning came out of it at that point…

But it did give very nice reddish brown (just as Dean promised) when heated. I just kept repeating with 10-g test skeins, it took 4 skeins to exhaust the bath. That’s a very good dye bath in my book! All the plant tops from those roots gave a brownish red-tinged yellow which is actually pretty nice, but I just tried that one one skein. Together they look like this – front to back its first to fourth root bath, then the plant tops all the way in the back:

rumexdyedwool

The result is quite pleasing, I think, and I began seeing similar plants just about everywhere. Another one that’s common around here is this one

rlongifolius

which is another member of the Rumex family, probably Rumex longifolius (dooryard dock) or Rumex crispus (curled dock). I’ve dug up some of these and dried the roots, to be saved for the meager dyeing days of winter.

FACTS – Rumex acetosa roots

Mordant 10% alum

Water Tap

Yarn Supersoft 575 m/100 g

Yarn:Dyestuff ratio 1:15 fresh roots was enough for 4 dye baths

Conclusion Lovely red-brown color

Possible improvements Not sure! This works!

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Bilskirner, the Final Prototypes

I’ve finally completed my prototypes for a child and adult version of the hat that I’ve decided to call Bilskirner. The design changed a bit since the first prototype… My family was not impressed with the rib edge on the first prototype, so my hands were tied. I had to make a garter edge in the final version, and I must admit it looks better.

hats1

hatsonly

In Norse mythology, Bilskirner is the home of the thunder god Thor. According to one of the Icelandic manuscripts called Grímnismál, Bilskirner with its 540 rooms is the largest building known. There are a lot of translations of Grímnismál (you can see some here), here’s one that I like:

Five hundred rooms and forty withal
I ween that in Bilskirnir be;
of all the halls  which on high are reared
the greatest I see is my son’s.

I imagine the huge home of the thunder god as an angular complex, and it feels like a match with my simple geometric unisex design.

And talking of a big angular complex, we went to one such and that’s actually where we took the top snapshots of us wearing the hats: on the roof of the new Moesgaard Museum outside Aarhus. I love the way this building rises out of the ground, it gives you the feeling that the ancient objects on display are somehow still under the ground

moesgaard

Plus, there’s the view from the top of the roof, you can see the land at the other side of the bay (Mols)

viewfromroof

We saw the exhibition there of the  Chinese terracotta soldiers that were found alongside the first emperor. They were truly beautiful!

terracotta

FACTS – BILSKIRNER HAT

Pattern Bilskirner, my pattern that is now ready for test knitting. Comment below if you want to test the pattern

Yarn Guldfaxe 100 m/50 g 100% alpaca

Needle 4.5 mm

Colors Gradient from madder to tansy, on a natural white background

Conclusion I’ve had good fun designing this hat. The rib edge on the first version drew the eye away from the color pattern, so I’m happy with the garter edge on the final version. At this point, all that remains is to race off to my dye pots to make some more color schemes!